Dielectric control of reverse intersystem crossing in thermally activated delayed fluorescence emitters (Record no. 800)
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042 ## - AUTHENTICATION CODE | |
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Authentication code | dc |
100 10 - MAIN ENTRY--PERSONAL NAME | |
Personal name | Gillett, Alexander J. |
Relator term | author |
9 (RLIN) | 1393 |
245 00 - TITLE STATEMENT | |
Title | Dielectric control of reverse intersystem crossing in thermally activated delayed fluorescence emitters |
260 ## - PUBLICATION, DISTRIBUTION, ETC. | |
Date of publication, distribution, etc. | 2022-10. |
500 ## - GENERAL NOTE | |
General note | /pmc/articles/PMC7613666/ |
500 ## - GENERAL NOTE | |
General note | /pubmed/35927434 |
520 ## - SUMMARY, ETC. | |
Summary, etc. | Thermally-activated delayed fluorescence (TADF) enables organic semiconductors with charge transfer (CT)-type excitons to convert dark triplet states into bright singlets via reverse intersystem crossing (rISC). However, thus far the contribution from the dielectric environment has received insufficient attention. Here, we study the role of the dielectric environment in a range of TADF materials with varying changes in dipole moment upon optical excitation. In dipolar emitters, we observe how environmental reorganisation after excitation triggers the full CT exciton formation, minimising the singlet-triplet energy gap, with the emergence of two (reactant-inactive) modes acting as a vibrational fingerprint of the CT product. In contrast, the dielectric environment plays a smaller role in less dipolar materials. The analysis of energy-time trajectories and their free-energy functions reveal that the dielectric environment significantly reduces the activation energy for rISC in dipolar TADF emitters, increasing the rISC rate by three orders of magnitude versus the isolated molecule. |
540 ## - TERMS GOVERNING USE AND REPRODUCTION NOTE | |
Terms governing use and reproduction | |
540 ## - TERMS GOVERNING USE AND REPRODUCTION NOTE | |
Terms governing use and reproduction | https://www.springernature.com/gp/open-research/policies/accepted-manuscript-termsUsers may view, print, copy, and download text and data-mine the content in such documents, for the purposes of academic research, subject always to the full Conditions of use: https://www.springernature.com/gp/open-research/policies/accepted-manuscript-terms |
546 ## - LANGUAGE NOTE | |
Language note | en |
690 ## - LOCAL SUBJECT ADDED ENTRY--TOPICAL TERM (OCLC, RLIN) | |
Topical term or geographic name as entry element | Article |
655 7# - INDEX TERM--GENRE/FORM | |
Genre/form data or focus term | Text |
Source of term | local |
700 10 - ADDED ENTRY--PERSONAL NAME | |
Personal name | Pershin, Anton |
Relator term | author |
9 (RLIN) | 1394 |
700 10 - ADDED ENTRY--PERSONAL NAME | |
Personal name | Pandya, Raj |
Relator term | author |
9 (RLIN) | 1395 |
700 10 - ADDED ENTRY--PERSONAL NAME | |
Personal name | Feldmann, Sascha |
Relator term | author |
9 (RLIN) | 1396 |
700 10 - ADDED ENTRY--PERSONAL NAME | |
Personal name | Sneyd, Alexander J. |
Relator term | author |
9 (RLIN) | 1397 |
700 10 - ADDED ENTRY--PERSONAL NAME | |
Personal name | Alvertis, Antonios M. |
Relator term | author |
9 (RLIN) | 1398 |
700 10 - ADDED ENTRY--PERSONAL NAME | |
Personal name | Evans, Emrys W. |
Relator term | author |
9 (RLIN) | 1399 |
700 10 - ADDED ENTRY--PERSONAL NAME | |
Personal name | Thomas, Tudor H. |
Relator term | author |
9 (RLIN) | 1400 |
700 10 - ADDED ENTRY--PERSONAL NAME | |
Personal name | Cui, Lin-Song |
Relator term | author |
9 (RLIN) | 1401 |
700 10 - ADDED ENTRY--PERSONAL NAME | |
Personal name | Drummond, Bluebell H. |
Relator term | author |
9 (RLIN) | 1402 |
700 10 - ADDED ENTRY--PERSONAL NAME | |
Personal name | Scholes, Gregory D. |
Relator term | author |
9 (RLIN) | 1403 |
700 10 - ADDED ENTRY--PERSONAL NAME | |
Personal name | Olivier, Yoann |
Relator term | author |
9 (RLIN) | 1404 |
700 10 - ADDED ENTRY--PERSONAL NAME | |
Personal name | Rao, Akshay |
Relator term | author |
9 (RLIN) | 1405 |
700 10 - ADDED ENTRY--PERSONAL NAME | |
Personal name | Friend, Richard H. |
Relator term | author |
9 (RLIN) | 1406 |
700 10 - ADDED ENTRY--PERSONAL NAME | |
Personal name | Beljonne, David |
Relator term | author |
9 (RLIN) | 1407 |
786 0# - DATA SOURCE ENTRY | |
Note | Nat Mater |
856 41 - ELECTRONIC LOCATION AND ACCESS | |
Uniform Resource Identifier | <a href="http://dx.doi.org/10.1038/s41563-022-01321-2">http://dx.doi.org/10.1038/s41563-022-01321-2</a> |
Public note | Connect to this object online. |
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